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iTunes meme! Snagged from everyone.

How many songs total: 6659
How many hours or days of music: 17.2 days
Most recently played: "Rufus' Welcoming Ceremony" - Nobuo Uematsu (Final Fantasy 7 soundtrack)
Most played: "I'm Not That Girl," "Popular," "Dancing Through Life," "Something Bad," "What is This Feeling," "The Wizard and I," "Dear Old Shiz," and "No One Mourns the Wicked" -- all from the Wicked soundtrack ... I was listening to the soundtrack on repeat pretty much all weekend long last weekend. ;D The rest of the soundtrack came in a very close second, lol. Truthfully, I've only recently started listening to music on iTunes, so the play count indicator isn't all that reliable.
Most recently added: "Code Monkey" - Jonathan Coulton, "This Woman's Work" - Maxwell, "Halo" - Beyonce, "Take Me Out" - Franz Ferdinand, "Nine in the Afternoon" - Panic! at the Disco, "Mad" - Ne-Yo, "Let it Rock" - Kevin Rudolf f Lil' Wayne, "Gravity" - Sara Bareilles, "Ain't Nothing Wrong with That" - Robert Randolph & the Family Band

SONG TITLE
First song: "Aaj Ki Raat" - Sonu Nigam, Mahalaxmi Lyer & Alisha Cinoi (Slumdog Millionaire soundtrack)
Last song: "867-5309" - Tommy TuTone

TIME
Shortest song: Three sound clips: "Come, Mr. Bigglesworth! *meow*" from Austin Powers, "To start, press any key. Where's the any key?!" from The Simpsons, and "And will there be any more splurging today?" from The Simpsons. All come in at 0:04.
Longest song: "Rite of Spring" by Stravinsky. 22:28

ALBUM
First album: Afterglow (Sarah McLachlan)
Last album: 98 Degrees and Rising (98 Degrees)

First song that comes up on Shuffle: "Hit me With Your Best Shot" - Pat Benatar

SEARCH
Death: 18
Life: 130
Love: 334
Hate: 22
You: 837
Sex: 4, though it should be noted that one instance is David Essex and the other three are actually "Sexy" not "sex"